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electrochemicalquantities.ttl
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electrochemicalquantities.ttl
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@prefix : <https://w3id.org/emmo/domain/electrochemistry#> .
@prefix owl: <http://www.w3.org/2002/07/owl#> .
@prefix rdf: <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix xml: <http://www.w3.org/XML/1998/namespace> .
@prefix xsd: <http://www.w3.org/2001/XMLSchema#> .
@prefix emmo: <http://emmo.info/emmo#> .
@prefix rdfs: <http://www.w3.org/2000/01/rdf-schema#> .
@prefix skos: <http://www.w3.org/2004/02/skos/core#> .
@prefix dcterms: <http://purl.org/dc/terms/> .
@prefix annotations: <http://emmo.info/emmo/top/annotations#> .
@base <https://w3id.org/emmo/domain/electrochemistry/electrochemicalquantities> .
<https://w3id.org/emmo/domain/electrochemistry/electrochemicalquantities> rdf:type owl:Ontology ;
owl:versionIRI <https://w3id.org/emmo/domain/electrochemistry/0.7.0-alpha/electrochemicalquantities> ;
owl:imports <http://emmo.info/emmo/1.0.0-beta5> ;
dcterms:abstract """This electrochemical quantities ontology is a domain of the Elementary Multiperspective Materials Ontology (EMMO). It is a specialized framework designed to represent and organize knowledge about electrochemical quantities. It is designed to integrate with the electrochemistry domain ontology or other ontologies from the EMMO ecosystem. The main focus of this ontology is to provide machine-readable descriptions of common electrochemical quantities, linking both to the larger descriptions of physical quantities in EMMO as well as other sources of information like the IEC, QUDT, Wikidata, etc. It should be used to support linked data generation in the electrochemistry domain."""@en ;
dcterms:license "https://creativecommons.org/licenses/by/4.0/legalcode" ;
owl:versionInfo "0.7.0-alpha" .
#################################################################
# Annotation properties
#################################################################
### http://emmo.info/emmo#EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f rdf:type owl:AnnotationProperty .
### http://purl.org/dc/terms/abstract
dcterms:abstract rdf:type owl:AnnotationProperty .
### http://purl.org/dc/terms/license
dcterms:license rdf:type owl:AnnotationProperty .
### http://purl.org/dc/terms/references
dcterms:references rdf:type owl:AnnotationProperty .
### http://purl.org/dc/terms/source
dcterms:source rdf:type owl:AnnotationProperty .
### http://www.w3.org/2004/02/skos/core#prefLabel
skos:prefLabel rdf:type owl:AnnotationProperty .
#################################################################
# Classes
#################################################################
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0141b5c2_9f15_46f4_82e6_92a104faa476
:electrochemistry_0141b5c2_9f15_46f4_82e6_92a104faa476 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "capacity delivered during a discharge process"@en ;
skos:hiddenLabel "AH-OUT"@en ,
"CapD"@en ,
"CapD/mAh"@en ,
"Q discharge/mA.h"@en ;
skos:prefLabel "DischargeCapacity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_02d2d1d1_241c_429b_b4e7_31f2c3dc4835
:electrochemistry_02d2d1d1_241c_429b_b4e7_31f2c3dc4835 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_c1c8ac3c_8a1c_4777_8e0b_14c1f9f9b0c6 ;
skos:prefLabel "D95ParticleSize"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634
:electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
skos:prefLabel "ElectrochemicalPerformanceQuantity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0335e3f6_d1d8_4daa_8376_a9285f1bc9f1
:electrochemistry_0335e3f6_d1d8_4daa_8376_a9285f1bc9f1 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q658700" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reaction_rate_constant"@en ;
skos:prefLabel "ReactionRateConstant"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a
:electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-09" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte"@en ;
skos:altLabel "OhmicOvervoltage"@en ,
"OhmicPolarization"@en ;
skos:prefLabel "OhmicOverpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_05012606_b93d_4016_bbc7_8a927efdf723
:electrochemistry_05012606_b93d_4016_bbc7_8a927efdf723 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of the negative electrode and the capacity of the positive electrode in a cell"@en ;
skos:altLabel "NToPRatio"@en ;
skos:prefLabel "NPRatio"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e
:electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_96f39f77_44dc_491b_8fa7_30d887fe0890 ;
emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1379273" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Surface_area"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a measure of the total area that the surface of a solid object occupies"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Surface_area"@en ;
skos:prefLabel "SurfaceArea"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_07e219c3_890f_488f_bd96_bee8e445d764
:electrochemistry_07e219c3_890f_488f_bd96_bee8e445d764 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric current that flows, at a particular value of the applied potential, in the absence of the substance whose electrode behaviour is being investigated, i.e. a \"blank\" solution."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/R05311"@en ;
rdfs:comment "I_{r}"@en ,
"The residual (or background) current may be subtracted from the total current to calculate the net faradaic current."@en ;
skos:altLabel "BackgroundCurrent"@en ;
skos:prefLabel "ResidualCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_07e219c3_890f_488f_bd96_bee8e445d764 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "Electric current that flows, at a particular value of the applied potential, in the absence of the substance whose electrode behaviour is being investigated, i.e. a \"blank\" solution."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0853b072_3b80_4864_8147_24ce35407ade
:electrochemistry_0853b072_3b80_4864_8147_24ce35407ade rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-07" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with an electrochemical reduction reaction"@en ;
skos:altLabel "CathodicPolarization"@en ;
skos:prefLabel "CathodicOverpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_0853b072_3b80_4864_8147_24ce35407ade ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "electrode polarization associated with an electrochemical reduction reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_08833ed2_6324_411a_b34b_fe64c44cd5ef
:electrochemistry_08833ed2_6324_411a_b34b_fe64c44cd5ef rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0141b5c2_9f15_46f4_82e6_92a104faa476 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the capacity obtained during constant current discharging of an electrochemical device"@en ;
skos:hiddenLabel "DC-Cap"@en ,
"DC-Cap/mAh"@en ;
skos:prefLabel "ConstantCurrentDischargeCapacity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef
:electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_6837b106_7220_4ec6_b7c9_d549d6163672
] ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a control limit placed on the rate of change of the cell voltage, dV/dt."@en ;
skos:altLabel "dV/dt"@en ;
skos:prefLabel "VoltageChangeLimit"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6
:electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
] ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the magnitude of the voltage step in step voltammetry and related techniques"@en ;
skos:prefLabel "StepSignalVoltage"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0c9655c6_6b0b_4819_a219_f286ad196fa9
:electrochemistry_0c9655c6_6b0b_4819_a219_f286ad196fa9 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_ffb73b1e_5786_43e4_a964_cb32ac7affb7 ;
rdfs:comment "inverse of internal resistance"@en ;
skos:prefLabel "InternalConductance"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_10763eb0_dbc9_4d34_bd1a_7b8996590d45
:electrochemistry_10763eb0_dbc9_4d34_bd1a_7b8996590d45 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "capacity delivered during a charge process"@en ;
skos:hiddenLabel "AH-IN"@en ,
"CapC"@en ,
"CapC/mAh"@en ,
"Q charge/mA.h"@en ;
skos:prefLabel "ChargeCapacity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_10eb778d_da60_4832_a355_4ee74baea650
:electrochemistry_10eb778d_da60_4832_a355_4ee74baea650 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "half the peak-to-peak amplitude of a sinusoidal alternating current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.A00310" ;
skos:prefLabel "AmplitudeOfAlternatingCurrent"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_129926b6_fc30_441d_b359_29b44c988514
:electrochemistry_129926b6_fc30_441d_b359_29b44c988514 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q759643" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The electrode electric potential range between which the substance is neither oxidized nor reduced."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_window"@en ;
skos:altLabel "ElectrochemicalStabilityWindow"@en ;
skos:prefLabel "ElectrochemicalWindow"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0
:electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.P04791"@en ;
rdfs:comment "The selectivity coefficient is determined by means of the potential difference of the ion- selective electrode in mixed solutions of the primary ion, A, and interfering ion, B (Fixed Interference Method) or, less desirably, in separate solutions of A and B (Separate Solution Method). The activities of the primary ion, A, and the interfering ion, B, at which K is determined should always be specified, as the value of K is defined by a modified Nikolsky-Eisenman equation. The smaller the value of K , the A,B greater the electrode’s preference for the primary ion, A."@en ;
skos:altLabel "SelectivityCoefficient"@en ,
"SelectivityConstant"@en ,
"SelectivityFactor"@en ;
skos:prefLabel "PotentiometricSelectivityCoefficient"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd
:electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_f6070071_d054_4b17_9d2d_f446f7147d0f
] ;
emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q62525" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the electrochemical potential is the chemical potential of an ion in the presence of an electric potential"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/E01945" ;
rdfs:comment "in quantum mechanical terms, electrochemical potential is defined as the energy level of the electron orbitals in the species that have a 50 percent probability of occupancy"@en ;
skos:prefLabel "ElectrochemicalPotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "the electrochemical potential is the chemical potential of an ion in the presence of an electric potential"@en ;
dcterms:source "Atkins and DePaula, Aktins' Physical Chemistry, 8th ed., p.952"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd ;
owl:annotatedProperty rdfs:comment ;
owl:annotatedTarget "in quantum mechanical terms, electrochemical potential is defined as the energy level of the electron orbitals in the species that have a 50 percent probability of occupancy"@en ;
dcterms:source "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004."
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b
:electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "algebraic sum of faradaic currents flowing through an electrode"@en ;
rdfs:comment "I"@en ;
skos:prefLabel "NetFaradaicCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "algebraic sum of faradaic currents flowing through an electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_16a5de33_a2ca_4563_80d4_6caeb08d97ca
:electrochemistry_16a5de33_a2ca_4563_80d4_6caeb08d97ca rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_900e357f_2ee3_425a_a0b6_322661117787 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-14" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "nominal property of an electrode, having values negative or positive according to the sign of the electrode potential, or neutral when the electrode potential is zero."@en ;
skos:prefLabel "Polarity"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_16a5de33_a2ca_4563_80d4_6caeb08d97ca ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "nominal property of an electrode, having values negative or positive according to the sign of the electrode potential, or neutral when the electrode potential is zero."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90
:electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1224527" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Diffusion_current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/D01722"@en ;
rdfs:comment "Diffusion current is governed by Fick’s Laws of diffusion. It is the principle on which many electroana- lytical methods are based, because the current is proportional to the bulk concentration of the diffusing species. I_{d} = z*F*A*D*\\grad(c)_{x=0}, where z is the electron number of an electrochemical reaction, F the Faraday constant, A the electrode surface area, D the diffusion coefficient of electroactive substance, and (∂c/∂x)x=0 the gradient of the amount concentration at the electrode surface position x = 0."@en ,
"I_{d}"@en ;
skos:prefLabel "DiffusionCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe
:electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_3789d3c5_77f4_456e_b7ed_40e670f47e52 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "rotational frequency of a rotating component in a rotating disk electrode"@en ;
emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "The rotating component can be the main rotating disk or a secondary ring as used in rotating ring disk electrodes."@en ;
skos:prefLabel "RotatingDiskSpeed"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "rotational frequency of a rotating component in a rotating disk electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1a104474_c326_4a29_ac26_26a05ac8f72c
:electrochemistry_1a104474_c326_4a29_ac26_26a05ac8f72c rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_02e894c3_b793_4197_b120_3442e08f58d1
] ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Duration between the time when an ion-selective electrode and an external reference electrode (the two completing the ion-selective electrode cell) are brought into contact with a sample solution (or the time at which the activity of the ion of interest in solution is changed) and the first time at which the slope of the cell potential vs. time plot (ΔE/Δt) becomes equal to a limiting value selected on the basis of the experimental conditions and/or requirements concerning accuracy."@en ;
rdfs:comment "Buck and Lindner suggest a slope of 0.6 mV min-1 ."@en ,
"""Previously defined response times t95 (corresponding to the 95% change of the potential span) and t* (to 1 mV from the steady value) require prior knowledge of steady-state E values that may not be available. These descriptive quantities underestimate practical response times of ion-selective electrodes in clinical applications where the total span may be narrower than 10 mV. The response time expressed in terms of ΔE/Δt (i.e., rate of cell potential variation with time) seems to be the best choice among non-ideal options. It can be related to t95
and t* through mathematical models, provided that the long-time potential- determining processes are identified."""@en ;
skos:prefLabel "ResponseTimeAtAnISE"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1a104474_c326_4a29_ac26_26a05ac8f72c ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "Duration between the time when an ion-selective electrode and an external reference electrode (the two completing the ion-selective electrode cell) are brought into contact with a sample solution (or the time at which the activity of the ion of interest in solution is changed) and the first time at which the slope of the cell potential vs. time plot (ΔE/Δt) becomes equal to a limiting value selected on the basis of the experimental conditions and/or requirements concerning accuracy."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1a104474_c326_4a29_ac26_26a05ac8f72c ;
owl:annotatedProperty rdfs:comment ;
owl:annotatedTarget "Buck and Lindner suggest a slope of 0.6 mV min-1 ."@en ;
dcterms:source "Buck, Richard P., and Erno Lindner. \"Recommendations for nomenclature of ionselective electrodes (IUPAC Recommendations 1994).\" Pure and Applied Chemistry 66.12 (1994): 2527-2536. DOI: 10.1351/pac199466122527"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6
:electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-02" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Overpotential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/O04358" ;
rdfs:comment "difference between the electrode potential with current flow, and the electrode potential without current flow, i.e. the equilibrium potential"@en ,
"overpotential is positive for oxidation reactions and negative for reduction reactions"@en ;
skos:altLabel "ElectrodePolarization"@en ,
"Overvoltage"@en ,
"PolarizationPotential"@en ;
skos:prefLabel "Overpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
owl:annotatedProperty rdfs:comment ;
owl:annotatedTarget "difference between the electrode potential with current flow, and the electrode potential without current flow, i.e. the equilibrium potential"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30
:electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_4dbe2b16_3e84_4049_898d_eb89bcc925a2
] ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-19" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a cell or battery [ or electrode or active material ] by its mass."@en ;
rdfs:comment "Can also be applied to electrodes."@en ;
skos:altLabel "GravimetricCapacity"@en ,
"SpecificChargeCapacity"@en ,
"SpecificElectricChargeCapacity"@en ;
skos:prefLabel "SpecificCapacity"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "quotient of the capacity of a cell or battery [ or electrode or active material ] by its mass."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6
:electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current that accompanies the adsorption of a species"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/A00159"@en ;
rdfs:comment "I_{ads}"@en ,
"The terms “adsorption current” and “limiting adsorption current” should not be applied to faradaic cur- rents that have been increased or decreased by adding a non-electroactive surfactant to a solution con- taining an electroactive substance, nor to currents resulting from the effect of adsorption or desorption on double-layer currents."@en ;
skos:prefLabel "AdsorptionCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "electric current that accompanies the adsorption of a species"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_21745019_2830_4395_bca7_15ddfd266673
:electrochemistry_21745019_2830_4395_bca7_15ddfd266673 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An ElectrochemicalQuantity that relates to the kinetics of a reaction."@en ;
skos:prefLabel "ElectrochemicalKineticQuantity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb
:electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of electric current due to transport of ions in the electric field between the electrodes"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/M03921"@en ;
rdfs:comment "I_{m}"@en ,
"The sign convention regarding current is such that the migration current is positive for the oxida- tion of a cation or the reduction of an anion and is negative for the reduction of a cation or for the oxidation of an anion. Hence, the migration current may either increase or decrease the total current observed. The migration current approaches zero as the transport number of the electroactive sub- stance is decreased by increasing the concentration of supporting electrolyte, and hence the conduc- tivity of the solution."@en ;
skos:prefLabel "MigrationCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "component of electric current due to transport of ions in the electric field between the electrodes"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc
:electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_cde4368c_1d4d_4c94_8548_604749523c6d ;
owl:disjointWith :electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744 ;
emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q6063658" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a measure of a substance's tendency towards ionic conduction"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Ionic_conductivity_(solid_state)"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.I03175"@en ;
skos:prefLabel "IonicConductivity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_25e20915_c35d_4bee_ad31_736235a79780
:electrochemistry_25e20915_c35d_4bee_ad31_736235a79780 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-25" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "[an indicator of the] electric current at which a battery is discharged"@en ;
rdfs:comment "in practice, the term CRate is often used to mean DRate"@en ,
"the discharge rate is calculated as the rated capacity divided by the corresponding discharge time which results in an electric current"@en ,
"the quantity DRate is not used for energy-decoupled batteries like Redox Flox batteries"@en ;
rdfs:seeAlso "CRate"@en ;
skos:altLabel "DischargeRate"@en ;
skos:prefLabel "DRate"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_25e20915_c35d_4bee_ad31_736235a79780 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "[an indicator of the] electric current at which a battery is discharged"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_25e20915_c35d_4bee_ad31_736235a79780 ;
owl:annotatedProperty rdfs:comment ;
owl:annotatedTarget "the discharge rate is calculated as the rated capacity divided by the corresponding discharge time which results in an electric current"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278
:electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_6837b106_7220_4ec6_b7c9_d549d6163672
] ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the rate of change of applied potential with time"@en ;
skos:altLabel "PotentialSweepRate"@en ,
"ScanRate"@en ,
"SweepRate"@en ;
skos:prefLabel "PotentialScanRate"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "the rate of change of applied potential with time"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af
:electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-12" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "sum of the absolute values of the potential differences resulting from anodic and cathodic polarizations of an electrochemical cell"@en ;
skos:altLabel "CellPolarizationPotential"@en ;
skos:prefLabel "CellPolarisationPotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "sum of the absolute values of the potential differences resulting from anodic and cathodic polarizations of an electrochemical cell"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2678a656_4a27_4706_8dde_b0a93e9b92fa
:electrochemistry_2678a656_4a27_4706_8dde_b0a93e9b92fa rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
skos:altLabel "RestingDuration"@en ,
"the duration during which an electrochemical device is kept at open-circuit conditions"@en ;
skos:prefLabel "RestingTime"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a
:electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
:electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "In electrochemical measurements, the voltage of an electrochemical cell to which a voltage signal is superimposed."@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "in EIS, an alternating voltage signal is superimposed to a baseline voltage, which can be the open circuit potential or a fixed cell voltage"@en ;
rdfs:seeAlso "ElectrochemicalImpedanceSpectroscopy" ;
skos:prefLabel "BaselineCellVoltage"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a ;
owl:annotatedProperty emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a ;
owl:annotatedTarget "in EIS, an alternating voltage signal is superimposed to a baseline voltage, which can be the open circuit potential or a fixed cell voltage"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2705525b_7512_48bf_825b_f2d0409bede4
:electrochemistry_2705525b_7512_48bf_825b_f2d0409bede4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time"@en ;
rdfs:comment "In practice, appropriate correction for the double-layer charging current is needed."@en ;
skos:prefLabel "QuarterTransitionTimePotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2705525b_7512_48bf_825b_f2d0409bede4 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_27b3799c_250c_4332_8b71_7992c4a7bb05
:electrochemistry_27b3799c_250c_4332_8b71_7992c4a7bb05 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "time of a measurement relative to the start of the test (t = 0)"@en ;
skos:hiddenLabel "TestTime/Sec"@en ,
"time/s"@en ;
skos:prefLabel "TestTime"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456
:electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5434687" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Faradaic_current"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current that results from the electrooxidation or electroreduction of an electroactive substance"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Faradaic_current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/F02321"@en ;
rdfs:comment "Current that is produced by other processes, for example by diffusion of charged species, is termed ‘non- faradaic current’."@en ,
"I_f"@en ;
skos:prefLabel "FaradaicCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "electric current that results from the electrooxidation or electroreduction of an electroactive substance"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2ab7af60_da58_4243_b3bc_cbb2155cac53
:electrochemistry_2ab7af60_da58_4243_b3bc_cbb2155cac53 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_46376e5d_9627_4514_9881_9e62083625c3 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "energy delivered by a deviced under some specific charge conditions"@en ;
skos:hiddenLabel "Energy charge/W.h"@en ,
"EnergyC"@en ,
"EnergyC/mWh"@en ,
"WH-IN"@en ;
skos:prefLabel "ChargeEnergy"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d
:electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.H02722"@en ;
rdfs:comment "E1/2 is used in techniques providing a sigmoidal wave-shaped current including DC voltammetry/polarography, normal pulse voltammetry, hydrodynamic voltammetry, and tast polarography."@en ,
"For quasi-reversible and irreversible electrode reactions, the value of E1/2 is also affected by the rate constant of the charge transfer reaction, the difference being greater than that caused by different diffusion coefficients."@en ,
"The quarter-wave potential, Ep/4, the three-quarter-wave potential, Ep3/4 , etc., may be similarly defined."@en ;
skos:prefLabel "HalfWavePotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2d896559_eee3_447c_9759_87c854a4266a
:electrochemistry_2d896559_eee3_447c_9759_87c854a4266a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A thermodynamically derived ElectrochemicalQuantity."@en ;
skos:prefLabel "ElectrochemicalThermodynamicQuantity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65
:electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of an electric current that is associated with the presence of an analyate in square-wave voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/S05897"@en ;
rdfs:comment "I_{SW}"@en ,
"The component may be faradaic (if the analyte is electroactive) or non-faradaic (if the analyte is surface-active). The simultaneous occurrence of both effects is quite common."@en ;
skos:prefLabel "SquareWaveCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "component of an electric current that is associated with the presence of an analyate in square-wave voltammetry"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_33e6986c_b35a_4cae_9a94_acb23248065c
:electrochemistry_33e6986c_b35a_4cae_9a94_acb23248065c rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_dd4a7f3e_ef56_466c_ac1a_d2716b5f87ec ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a target quantity in a control system"@en ;
skos:altLabel "ControlledQuantity"@en ,
"SetQuantity"@en ;
skos:prefLabel "ControlProperty"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d
:electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the magnitude of a current pulse applied to an electrochemical cell during pulsed potentiometry and related techniques"@en ;
skos:altLabel "PulseMagnitudeCurrent"@en ;
skos:prefLabel "MagnitudeOfCurrentPulse"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_37b24a94_cae0_4d7a_9519_9f7692dec607
:electrochemistry_37b24a94_cae0_4d7a_9519_9f7692dec607 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
skos:prefLabel "Diffusivity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_37c38b7e_9ded_481a_85fd_a467f1ee2b9f
:electrochemistry_37c38b7e_9ded_481a_85fd_a467f1ee2b9f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_10763eb0_dbc9_4d34_bd1a_7b8996590d45 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the capacity obtained during constant current charging of an electrochemical device"@en ;
skos:hiddenLabel "CC-Cap"@en ,
"CC-Cap/mAh"@en ;
skos:prefLabel "ConstantCurrentChargeCapacity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_382b10dc_83aa_4e77_a1d5_1edd06fd1e05
:electrochemistry_382b10dc_83aa_4e77_a1d5_1edd06fd1e05 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "in dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "Typical examples of imposed potential programmes in dynamic voltammetric techniques resulting in peak-shaped responses are linear-scan voltammetry, cyclic voltammetry, ac voltammetry, differential pulse voltammetry, square-wave voltammetry, stripping voltammetry, and derivative techniques."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/P04457"@en ;
rdfs:comment "I_{p}"@en ,
"Since the concentration of an electroactive substance at the electrode-solution interface decreases mono- tonically, the faradaic current due to its electrooxidation or electroreduction increases monotonically with time because of the increasing concentration gradient of the electroactive substance, the concentra- tion of which remains constant in the bulk. The maximum current value is passed when the transport rate of electroactive substance to the electrode-solution interface starts to be lower than the rate at which it is removed by reaction at the electrode. The result of these two competing processes leads to the peak- shaped I-E dependence."@en ;
skos:prefLabel "PeakCurrent"@en .
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owl:annotatedTarget "in dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_39a44af0_0e1a_4859_b550_bdabad64386e
:electrochemistry_39a44af0_0e1a_4859_b550_bdabad64386e rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_affe07e4_e9bc_4852_86c6_69e26182a17f ;
skos:prefLabel "AmbientThermodynamicTemperature"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3b938708_e7e4_4ac0_a959_9c04306302e7
:electrochemistry_3b938708_e7e4_4ac0_a959_9c04306302e7 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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owl:disjointWith :electrochemistry_f9e1c862_c510_4b11_9141_bc91045df817 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "thickness of the coating before any additional treatment is applied"@en ;
skos:prefLabel "CoatingThickness"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28
:electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-33" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of change in open-circuit voltage of a cell or battery by the corresponding change in temperature."@en ;
skos:prefLabel "TemperatureCoefficientOfTheOpenCircuitVoltage"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28 ;
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owl:annotatedTarget "quotient of change in open-circuit voltage of a cell or battery by the corresponding change in temperature."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56
:electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.P04947"@en ;
rdfs:comment "The pulse duration includes the sampling interval."@en ;
skos:prefLabel "PulseDuration"@en .
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owl:annotatedSource :electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 ;
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owl:annotatedTarget "time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques"@en ;
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] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c
:electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c1c8ac3c_8a1c_4777_8e0b_14c1f9f9b0c6 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "in particle size distribution measurements, the mass-median-diameter, considered to be the average particle size by mass"@en ;
skos:prefLabel "D50ParticleSize"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3e54f9e3_a31d_4821_9bfb_ef953a42c35b
:electrochemistry_3e54f9e3_a31d_4821_9bfb_ef953a42c35b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d ,
:electrochemistry_74de2c33_84fc_4c2f_afe1_56d169149114 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum current approved for pulse discharge of an electrochemical device"@en ;
skos:prefLabel "MaximumPulseDischargeCurrent"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_457aed58_6e7e_42d5_9d78_b424c8d60aa3
:electrochemistry_457aed58_6e7e_42d5_9d78_b424c8d60aa3 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the percentage of the total discharge capacity that is obtained during a constant current discharge process"@en ;
skos:hiddenLabel "DC-Per"@en ,
"DC-Per/%"@en ;
skos:prefLabel "ConstantCurrentDischargePercentage"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46376e5d_9627_4514_9881_9e62083625c3
:electrochemistry_46376e5d_9627_4514_9881_9e62083625c3 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
emmo:EMMO_31ec09ba_1713_42cb_83c7_b38bf6f9ced2 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-21"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "amount of energy that can be stored in a device under specific conditions"@en ;
skos:altLabel "BatteryEnergy"@en ;
skos:hiddenLabel "Energy/mWh"@en ,
"Watt-hr"@en ,
"mWatt-hr"@en ;
skos:prefLabel "EnergyStorageCapability"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_47287d09_6108_45ca_ac65_8b9451b1065e
:electrochemistry_47287d09_6108_45ca_ac65_8b9451b1065e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_5eae657f_5914_4252_85c6_3fc772dea113 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum amount concentration of a species in a phase, either imposed or naturally occurring"@en ;
skos:prefLabel "MaximumConcentration"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4747c51d_86ab_4684_a4fb_b05f5c405ea3
:electrochemistry_4747c51d_86ab_4684_a4fb_b05f5c405ea3 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_82fce40c_434d_4640_a3d2_e26379b6acae ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the minimum allowable temperature"@en ;
skos:prefLabel "MiniumumTemperature"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd
:electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "area of electrode - solution interface."@en ;
rdfs:comment "A"@en ,
"""The geometric area, A_{geom} , is the interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces.
The real (true) area, A_{real}, takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods. The electroactive area is the area calculated from experiments with model electroactive species and may be different from the real surface area in cases where not all of the surface is electrochemically active or accessible."""@en ;
skos:prefLabel "ElectrodeSurfaceArea"@en .
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owl:annotatedSource :electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
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] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_482173dc_7779_4f12_982c_b19f2cda2dac
:electrochemistry_482173dc_7779_4f12_982c_b19f2cda2dac rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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skos:prefLabel "NumberOfCellsConnectedInParallel"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4882cf2f_aab7_4a3a_a103_7f56b55fbed3
:electrochemistry_4882cf2f_aab7_4a3a_a103_7f56b55fbed3 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a cell or battery [ or electrode or active material ] obtained during a charge process by its mass."@en ;
skos:hiddenLabel "SpeCapC"@en ,
"SpeCapC/mAh/g"@en ;
skos:prefLabel "SpecificChargeCapacity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47
:electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_900e357f_2ee3_425a_a0b6_322661117787 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-35" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ability of a cell or battery to retain capacity on open circuit under specified conditions."@en ;
rdfs:seeAlso "SelfDischarge"@en ;
skos:altLabel "CapacityRetention"@en ;
skos:prefLabel "ChargeRetention"@en .
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owl:annotatedSource :electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
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] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b
:electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An ElectrochemicalQuantity related to the transport of mass, charge, or energy."@en ;
skos:prefLabel "ElectrochemicalTransportQuantity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b
:electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the quotient of the energy of an energy-storage device or system and its volume"@en ;
skos:altLabel "EnergyDensity"@en ;
skos:prefLabel "EnergyDensityOfStorage"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4b18c3f9_df10_4259_adb4_cd10842ff0be
:electrochemistry_4b18c3f9_df10_4259_adb4_cd10842ff0be rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the time that elapses between the instants at which two successive drops of liquid metal are detached from the tip of the capillary."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.D01862"@en ;
skos:prefLabel "DropTimeInPolarography"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc
:electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The magnitude of a voltage pulse applied to an electrochemical cell during pulsed amperometry and related techniques."@en ;
skos:altLabel "PulseMagnitudePotential"@en ;
skos:prefLabel "MagnitudeOfPotentialPulse"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d
:electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_17b031fb_4695_49b6_bb69_189ec63df3ee ;
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltage between the terminals of an electrochemical cell"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.A00424"@en ;
rdfs:comment "difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell"@en ;
skos:altLabel "AppliedPotential"@en ;
skos:hiddenLabel "Ecell/V"@en ,
"Voltage/V"@en ,
"Volts"@en ;
skos:prefLabel "CellVoltage"@en .
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owl:annotatedSource :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
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] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
owl:annotatedProperty rdfs:comment ;
owl:annotatedTarget "difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a
:electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-46" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "[an indicator of the] electric current at which a battery is charged towards the end of charge"@en ;
rdfs:comment "the quantity CRate is not used for energy-decoupled batteries like Redox Flox batteries"@en ;
skos:altLabel "FinishingChargeRate"@en ;
skos:prefLabel "FinishingCRate"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
owl:annotatedTarget "[an indicator of the] electric current at which a battery is charged towards the end of charge"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_520995f8_ec9c_4b3c_bb64_2cd691947379
:electrochemistry_520995f8_ec9c_4b3c_bb64_2cd691947379 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "density after calendering"@en ;
skos:prefLabel "CalenderedDensity"@en .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2
:electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
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owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_77e9dc31_5b19_463e_b000_44c6e79f98aa
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skos:prefLabel "ResidualActiveMass"@en .
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owl:annotatedSource :electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2 ;
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] .
### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_52ac73c7_763c_4fda_93cd_a2db9dfc2dab
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rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
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emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "time interval during which the current is measured in pulse voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.S05465"@en ;
skos:prefLabel "SamplingInterval"@en .
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] .