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# Radar charts illustrating the relative differences between the average experimental and computed NMR parameters values for RbNb$_{2}$O$_{5}$F (\textit{a}) and RbTa$_{2}$O$_{5}$F (\textit{b}). The average NMR parameter values are those in bold italic from \textbf{Table~\ref{tab:table4}}. The axes are scaled in \% and features the scoring functions $f$\{$\langle \delta_{iso}\rangle$; $^{19}$F\}, $f$\{$\langle \delta_{CSA}\rangle$; $^{19}$F\}, $f$\{$\langle \delta_{iso}\rangle$; $^{87}$Rb\}, $f$\{$\langle C_{Q}\rangle$; $^{87}$Rb\}, $f$\{$\langle \eta_{Q}\rangle$; $^{87}$Rb\}, $f$\{$\langle \delta_{iso}\rangle$; $^{93}$Nb\}, $f$\{$\langle C_{Q}\rangle$; $^{93}$Nb\}, and $f$\{$\langle \eta_{Q}\rangle$; $^{93}$Nb\}. The unit cell and 2$\times$2$\times$2 supercell charts are colored orange and teal, respectively.